This document specifies a potentiometric or visual titration method for the determination of manganese content in alloyed steels. The method is applicable to manganese mass fractions between 2% and 25%. Vanadium and cerium interfere with the determination. If the mass fraction of cerium in the sample is less than 0.01%, or the mass fraction of vanadium in the sample is less than 0.005%, the interference is negligible, otherwise theoretical corrections are necessary.